Examination & interpretation of the seismic tomography data in respect to "up-lift" phenomena and stress-induced anisotropy

In recent years, global concerns about greenhouse gas emissions have stimulated considerable interest in carbon capture and storage (CCS) as a climate change mitigation option that can be used to reduce man-made CO2 emissions. This is achieved by separating and capturing CO2 from emission sources, then injecting and storing it in the subsurface. However, CCS requires the secure retention of CO2 in geological formations over thousands of years. To achieve this, there are two distinct purposes for undertaking monitoring at CO2 storage sites: (1) to ensure conformance by tracking the pressure buildup and CO2 inside the storage complex, thereby helping to indicate the long term security of the site (‘integrity monitoring’) and (2) to ensure containment by triggering timely control measures to mitigate any unexpected leakage, helping to demonstrate the current security situation, especially in the area surrounding the storage complex (‘assurance monitoring’) (Bourne et al. 2014). A significant issue for storage security is the geomechanical response of the reservoir. Concerns have been raised that geomechanical deformation induced by CO2 injection connected with pressure increase will create or reactivate fracture networks in the sealing caprocks, providing a pathway for CO2 leakage (Verdon et al. 2013). Several geochemical and geophysical (such as time-lapse seismic) techniques allow monitoring the regional distribution of CO2 in the storage complexes, seal integrity and the pressure evolution in response to the injection and therefore can be used to verify storage conformance and are valuable tools for integrity monitoring (IEA 2012). The most significant environmental risk associated with CCS technology is gradual leakage through undetected faults, fractures, or wells, or the potential problems caused by leakages due to injection well failure or leakages up through an abandoned well. In addition, other issues include the influence of a CO2 plume, reservoir pressure changes, and geomechanical changes in the multilayered subsurface with minor and major faults as migration paths. There are injection-induced stress, strain, deformations, and potential microseismic events resulting from changes in reservoir pressure and temperature and unwanted unelastic mechanical changes that might reduce sequestration efficiency and cause concerns in the local community

Characteristics of dissolved and atmospheric methane concentrations along a freshwater-seawater transect from the River Elbe into the North Sea

Surface waters are known to be significant sources of greenhouse gases (CH4 and CO2), but our understanding of large scale patterns is still incomplete. The greenhouse gases in rivers originate both from in-stream processes and interactions with the catchment. For coastal seas, rivers are suspected to be one of the main source of greenhouse gases, while the role of the interjacent tidal flats is still ambiguous. Especially the reaction of the entire system on terrestrial hydrological extremes such as low flow situations are still under consideration. The functional understanding of such events and their impacts on the water chemistry along its transition pathway in the terrestrial and limnic compartment as well as in the coastal marine environment is crucially needed for the evaluation of its relevance in the Earth system. As part of a MOSES campaign (Modular Observation Solutions for Earth Systems) spanning disciplines as well as earth system compartments we investigated the aquatic as well as the atmospheric compartemt in and above the Elbe River from inland waters through the tidal section of the river and the estuary to the North Sea with the goal to explore spatial heterogeneity of CO2 and CH4 concentrations in the water and in ambient air above the water during a low water period in summer 2020. Overall, dissolved CH4 concentrations ranged over three orders of magnitude. Along the freshwater part of the transect, dissolved CH4 increased and weirs and harbors appeared to be hot spots of elevated CH4 concentrations both for the dissolved and atmospheric phase. We observed a longitudinal gradient of CO2 in the river which was closely linked to primary production. In the estuary and the marine part, dissolved CH4 concentrations of the transect were determined by the variability of temperature and salinity. Correlations with other water parameters revealed the complex regulation of dissolved CH4 concentrations along the freshwater-seawater continuum. For atmospheric CH4 above the North Sea, wind direction and wind speed proved to be crucial. Besides the typical diurnal fluctuations of atmospheric CO2 and CH4, an observed link between dissolved and atmospheric concentrations has to be further clarified

The challenge of sensor selection, long term-sensor operation and data evaluation in inter- -institutional long term monitoring projects - lessons learned in the MOSES project -

Measuring environmental variables over longer times in coastal marine environments is a challenge in regard to sensor maintenance and data processing of continuously produced comprehensive datasets. In the project “MOSES” (Modular Observation Solutions for Earth Systems), this procedure became even more complicated because seven large Helmholtz centers from the research field Earth and Environment (E&E) within the framework of the German Ministery of Educatiopn and Research (BMBF) work together to design and construct a large scale monitoring network across earth compartments to study the effects of short-term events on long term environmental trends. This requires the development of robust and standardized automated data acquisition and processing routines, to ensure reliable, accure and precise data. Here, the results of two intercomparison workshops on senor accuracy and precicion for selected environmental variables are presented. Environmental sensors which were to be used in MOSES campaigns on hydrological extremes (floods and draughts) in the Elbe catchment and the adjacent coastal areas in the North Sea in 2019 to 2020 were compared for selected parameters (temperature, salinity, chlorophyll-A, turbidity and methane) in the same experimentally controlled water body, assuming that all sensors provide comparable data. Results were analyzed with respect to individual sensor accuracy and precision related to an “assumed” real value as well as with respect to a cost versus accuracy/precision index for measuring specific environmental data. The results show, that accuracy and precision of sensors do not necessarily correlate with the price of the sensors and that low cost sensors may provide the same or even higher accuracy and precision values as even the highest price sensor types

Influence of wind speed and wind direction above the sea surface on the diffusive methane flux and the atmospheric methane concentration at the North Sea

The estimations of the diffusive methane flux from the water phase into the atmosphere in coastal waters is relevant for a better estimate of the atmospheric greenhouse-gas budget. Unfortunately, so far, the numerical determination of the fluxes has a high level of uncertainty in coastal waters. To improve the estimation of coastal methane fluxes, not only a high temporal and spatial sampling resolution of the dissolved methane in the water are required. Besides, also the atmospheric methane concentration and the wind speed and wind direction above the surface is important. In most cases, these atmospheric data are obtained from near-by atmospheric and meteorologic monitoring stations. In this study, we measured wind speed, direction and atmospheric methane local directly on board of three research vessel cruising in the southern North Sea within the MOSES project and compared the effects of local versus remote measurements of these data on the flux data. In addition, using the wind direction and speed, we try to assess the origin of the atmospheric methane measured in the study area. Using these “improved” data sets, we discuss if local measurements of auxiliary data provide better insights in the determining factors of the methane flux, and thus also improve the regional aquatic methane budget

TRA of DigiMon components

The DigiMon project aims to develop an affordable, flexible, societally embedded and smart monitoring system for industrial scale subsurface CO2 storage. For this purpose, the DigiMon system is to combine various types of measurements in integrated workflows. In this report, we describe the process of conducting the Technology Readiness Assessment (TRA) of various measurement techniques. We report on the identification, description and assessment of these measurement techniques as Critical Technology Elements (CTEs) being part of the DigiMon system

Nutrient and carbon dynamics along the river-estuary-ocean continuum on Central European scale

Nutrient and carbon dynamics within the river-estuary-coastal water systems are key processes to understand the matter fluxes from the terrestrial environment to the ocean. In a large-scale study we analysed those dynamics with the focus of the prevailing low water conditions by following a sampling approach based on the travel time of water. We started with a nearly Lagrangian sampling along the River Elbe (German part; 580 km within 8 days travel time). After a subsequent investigation of the estuary, the plume of the river was followed by raster sampling the German Bight (North Sea) using three ships simultaneously. In the river, intensive growth of phytoplankton was determined connected with high oxygen saturation and pH values as well as under-saturation of CO2, whereas concentrations of dissolved nutrients declined. In the estuary, the Elbe shifted from an autotrophic to a heterotrophic system: Phytoplankton died off upstream of the salinity gradient causing minima in oxygen saturation and pH, supersaturation of CO2, and a release of nutrients. In the coastal region, phytoplankton and nutrient concentrations were low, oxygen close to saturation, and pH in a typical marine range. We detected a positive relationship between pH values and oxygen saturation and a negative one between pCO2 and oxygen saturation. Corresponding to the significant particulate nutrient flux via phytoplankton, flux rates of dissolved nutrients from the river into the estuary were low and determined by depleted concentrations. In contrast, fluxes from the estuary to the coastal waters were higher and the pattern was determined by tidal currents. Overall, the presented observation approach is appropriate to better understand land-ocean fluxes, particularly if it is performed under different hydrological conditions including extremes and seems to be suitable to investigate the impact of such events in freshwater on coastal systems in future. The study was conducted within the frame of the Helmholtz MOSES initiative (Modular Observation Solutions for Earth Systems) targeting processes and impacts of hydrological extremes

First implementation of a new cross-disciplinary observation strategy for heavy precipitation events from formation to flooding

Heavy Precipitation Events (HPE) are the result of enormous quantities of water vapor being transported to a limited area. HPE rainfall rates and volumes cannot be fully stored on and below the land surface, often leading to floods with short forecast lead times that may cause damage to humans, properties, and infrastructure. Toward an improved scientific understanding of the entire process chain from HPE formation to flooding at the catchment scale, we propose an elaborated event-triggered observation concept. It combines flexible mobile observing systems out of the fields of meteorology, hydrology and geophysics with stationary networks to capture atmospheric transport processes, heterogeneous precipitation patterns, land surface and subsurface storage processes, and runoff dynamics. As part of the Helmholtz Research Infrastructure MOSES (Modular Observation Solutions for Earth Systems), the effectiveness of our observation strategy is illustrated by its initial implementation in the Mueglitz river basin (210 km$^2$), a headwater catchment of the Elbe in the Eastern Ore Mountains with historical and recent extreme flood events. Punctual radiosonde observations combined with continuous microwave radiometer measurements and back trajectory calculations deliver information about the moisture sources, and initiation and development of HPE. X-band radar observations calibrated by ground-based disdrometers and rain gauges deliver precipitation information with high spatial resolution. Runoff measurements in small sub-catchments complement the discharge time series of the operational network of gauging stations. Closing the catchment water balance at the HPE scale, however, is still challenging. While evapotranspiration is of less importance when studying short-term convective HPE, information on the spatial distribution and on temporal variations of soil moisture and total water storage by stationary and roving cosmic ray measurements and by hybrid terrestrial gravimetry offer prospects for improved quantification of the storage term of the water balance equation. Overall, the cross-disciplinary observation strategy presented here opens up new ways toward an integrative and scale-bridging understanding of event dynamics

Project report on WP1 outcomes relevant to other WPs

This report summaries some of the key technologies that have been studied and developed through WP1 with the purpose of transferring these finding to other WPs in the DigiMon project. The objective of the DigiMon project is to develop an early-warning system for Carbon Capture and Storage (CCS) which utilises a broad range of sensor technologies including Distributed Acoustic Sensing (DAS). While the system is primarily focused on the CCS projects located in the shallow offshore environment of the North Sea, it is also intended to be adaptable to onshore settings. Some of the key areas that the systems will monitor include the movement of the plume within the reservoir, well integrity and CO2 leakage into the overburden. A combination of different methods will be adopted to monitor these key areas, which include active and passive seismics, gravimetry, temperature and chemical sensing. This report focuses on technology and methods which have been developed by the DigiMon project and is not intended as a technology review, which is instead the focus of the DigiMon deliverable 2.3 Technology Readiness Assessment

Critical technology elements (WP1)

The overall objective of the DigiMon project is to “accelerate the implementation of CCS by developing and demonstrating an affordable, flexible, societally embedded and smart Digital Monitoring early warning system”, for monitoring any CO2 storage reservoir and subsurface barrier system. Within the project the objective of WP1 was to develop individual technologies, data acquisition, analysis techniques and workflows in preparation for inclusion in the DigiMon system. The technologies and data processing techniques developed as part of WP1 include distributed fibre-optic sensing (DFOS) for seismic surveys and chemical sensing, 4D gravity and seafloor deformation measurements, a new seismic source and seismic monitoring survey design. For these technologies the key targets for WP1 were • Develop individual components of the system to raise individual technology readiness levels (TRLs), • Validate and optimise processing software for individual system components, • Develop an effective Distributed Acoustic Sensing (DAS) data interpretation workflow. This work was performed with the expected outcomes of • Raising the DAS TRL for passive seismic monitoring, • An assessment the feasibility of using Distributed Chemical Sensing (DCS) for CO2 detection, • Reducing the cost of 4D gravity and seafloor deformation measurements

Remote sensing of geomorphodiversity linked to biodiversity — part III: traits, processes and remote sensing characteristics

Remote sensing (RS) enables a cost-effective, extensive, continuous and standardized monitoring of traits and trait variations of geomorphology and its processes, from the local to the continental scale. To implement and better understand RS techniques and the spectral indicators derived from them in the monitoring of geomorphology, this paper presents a new perspective for the definition and recording of five characteristics of geomorphodiversity with RS, namely: geomorphic genesis diversity, geomorphic trait diversity, geomorphic structural diversity, geomorphic taxonomic diversity, and geomorphic functional diversity. In this respect, geomorphic trait diversity is the cornerstone and is essential for recording the other four characteristics using RS technologies. All five characteristics are discussed in detail in this paper and reinforced with numerous examples from various RS technologies. Methods for classifying the five characteristics of geomorphodiversity using RS, as well as the constraints of monitoring the diversity of geomorphology using RS, are discussed. RS-aided techniques that can be used for monitoring geomorphodiversity in regimes with changing land-use intensity are presented. Further, new approaches of geomorphic traits that enable the monitoring of geomorphodiversity through the valorisation of RS data from multiple missions are discussed as well as the ecosystem integrity approach. Likewise, the approach of monitoring the five characteristics of geomorphodiversity recording with RS is discussed, as are existing approaches for recording spectral geomorhic traits/ trait variation approach and indicators, along with approaches for assessing geomorphodiversity. It is shown that there is no comparable approach with which to define and record the five characteristics of geomorphodiversity using only RS data in the literature. Finally, the importance of the digitization process and the use of data science for research in the field of geomorphology in the 21st century is elucidated and discussed